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Certainly yes; however, our advice would be no because the consequences will lead to a more intensifying fire due to overflow of oxygen.
On the contrary, desperate times call for drastic measures.
Therefore, if you must break the glass, then use anything pointed and sturdy; strike at any corner of the double-glazed windowpane for making your way out.
There have been incidents when people died as they remained trapped in a room that had its escape route barricaded by a double-glazed window.
A chair thrown for breaking double glazing windows was deflected, leaving just a barely visible scratch!
Read more on how to turn your double-glazed windows unique from the rest.
A fireman’s advice for breaking double-glazed windows is hitting any corner of the glass with a tremendous force using a hammer.
Alternatively, use the sharp portion of a diamond by sticking it at either of the bottom corners but not close to the frame. Next, ram using something like a fire-extinguisher against the sharp and small diamond to shatter the glass into thousands of granular pieces!
Others have advised not to perform any such activity, such as breaking down glasses, but using the emergency staircase and leaving the premises.